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DTSTAMP:20250211T095453
DTSTART;TZID=America/Detroit:20250218T160000
SUMMARY:Workshop / Seminar:Organometallic Single-Molecule Magnets Containing Radicals and Bismuth
DESCRIPTION:Single-molecule magnets (SMMs) are molecules that possess an energy barrier to spin inversion\, giving rise to slow magnetic relaxation and magnetic hysteresis. To realize their intriguing potential applications\, ranging from molecular spintronics\, quantum computing\, to high-density information storage\, spin-reversal barriers (Ueff) and magnetic blocking temperatures (TB) must be increased. Lanthanide ions are especially well-suited for the design of SMMs due to their large magnetic moments and magnetic anisotropy that originate from strong spin-orbit coupling of the 4f orbitals. One effective methodology to boost blocking temperatures of multinuclear compounds is to generate strong magnetic exchange between lanthanide centers using radical bridging ligands. In the event of strong magnetic exchange coupling\, undesirable relaxation pathways such as quantum tunneling of the magnetization can be suppressed. Here\, the first isolation of the bisbenzimidazole radical anion (Bbim3−•) and its use in radical-bridged SMMs will be discussed\, Fig. 1.1\,2 Furthermore\, the isolation of the first fluoflavine radicals will be presented.3 A second approach to strong coupling employs heavy p-block elements since their diffuse valence orbitals facilitate better penetration of the core electron density of the lanthanide ions relative to diamagnetic ligands comprising lighter p-block elements. Here\, we will present the first lanthanide bismuth cluster SMMs containing a [Ln2Bi6] heterometallocubane core\, Fig. 1. We will also show that the Bi23−• radical anion can be tamed with rare earth ions to give the first SMMs featuring bismuth radicals\, Fig. 1.4\,5 We also synthesized complexes with diamagnetic 89Y (I = ½) to gain insight into the electronic structure and spin density distribution.6-9 The organometallic rare earth chemistry has been further advanced by the isolation of the first guanidinate complexes featuring a weakly coordinated tetraphenylborate anion\,10 which have ramifications for both magnet design and reactivity studies.11\,12\n\nReferences. (1) Benner\, F.\; Demir\, S. Chem. Sci. 2022\, 13\, 5818. (2) Benner\, F.\; La Droitte\, L.\; Cador\, O.\; Le Guennic\, B.\; Demir\, S.\; Chem. Sci. 2023\, 14\, 5577. (3) Benner\, F.\; Demir\, S. J. Am. Chem. Soc. 2024\, 146\, 26008. (4) Zhang\, P.\; Benner\, F.\; Chilton\, N. F.\; Demir\, S. Chem 2022\, 8\, 717. (5) Zhang\, P.\; Nabi\, R.\; Staab\, J. K.\; Chilton\, N. F.\; Demir\, S. J. Am. Chem. Soc. 2023\, 145\, 9152. (6) Pugliese\, E. R.\; Benner\, F.\; Demir\, S. Chem. Commun. 2023\, 59\, 14791. (7) Delano IV\, F.\; Castellanos\, E.\; McCracken\, J.\; Demir\, S. Chem. Sci. 2021\, 12\, 15219. (8) Benner\, F.\; Demir\, S. Inorg. Chem. Front. 2023\, 10\, 4981. (9) Delano IV\, F.\; Benner\, F.\; Jang\, S.\; Greer\, S. M.\; Demir\, S. Chem. Sci. 2024\, 15\, 13389. (10) Delano IV\, F.\, Demir\, S. Cryst. Growth Des. 2023\, 23\, 3134. (11) Delano IV\, F.\; Deshapriya\, S.\; Demir\, S. Inorg. Chem. 2024\, 63\, 9659. (12) Delano IV\, F.\; Demir\, S. Angew. Chem. Int. Ed. 2024. Early View. DOI:10.1002/anie.202417217.
UID:125070-21854320@events.umich.edu
URL:https://events.umich.edu/event/125070
CLASS:PUBLIC
STATUS:CONFIRMED
CATEGORIES:Chemistry,Inorganic Chemistry
LOCATION:Chemistry Dow Lab - 1640
CONTACT:
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BEGIN:VEVENT
DTSTAMP:20250127T090445
DTSTART;TZID=America/Detroit:20250218T160000
DTEND;TZID=America/Detroit:20250218T170000
SUMMARY:Meeting:Psycholinguistics
DESCRIPTION:The psycholinguistics discussion group is a meeting of several lab groups from Linguistics\, Psychology\, and other departments that all share common interests in language processing\, including comprehension\, production\, and acquisition. The discussion group is an informal venue for presenting research findings\, for developing new ideas\, and for connecting with the many language scientists across the University who are interested in the psychology and neuroscience of human language.
UID:131899-21869373@events.umich.edu
URL:https://events.umich.edu/event/131899
CLASS:PUBLIC
STATUS:CONFIRMED
CATEGORIES:Discussion Group,Language Processing,Psychology
LOCATION:Off Campus Location - 403 Lorch
CONTACT:
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BEGIN:VEVENT
DTSTAMP:20250303T063132
DTSTART;TZID=America/Detroit:20250218T160000
DTEND;TZID=America/Detroit:20250218T170000
SUMMARY:Careers / Jobs:SMBC Info Session: Meet Our Senior Leaders & Explore Your Future in Global Banking 1
DESCRIPTION:We invite all sophomores\, juniors\, and seniors who are completing an undergraduate degree.&nbsp\; We understand how the recruitmentprocess can be overwhelming at times. This session was designed with yourbest interests in mind. From learning about our SMBC brand\, our businesses\, and Intern and Analyst programs to gaining insights into the interview process\, we are confident that you will be better prepared for your career journey.Come get to know us.At SMBC\, we are growing and transforming alongside our clients. This means we need experienced collaborators to help us continue on our path of globalization\, diversification\, and expansion. We are developing teams of dynamic seekers who are looking to build something great and lasting for themselves\, our clients\, and our company.During our Q&amp\;A session\, you will have the unique opportunity to hear from a senior business leader at SMBC. Michael Mills is an Executive Director at SMBC Nikko SecuritiesAmerica. Michael Mills joined SMBC Nikko in 2021 as an ExecutiveDirector of the Investment Grade Trading desk. With a specialization in trading the full curve USD Autos sector\, Michael brings a wealth of industry knowledge and global experience from his tenure in New York\, London\, and Hong Kong.Before joining SMBC\, Michael held senior trading positions at HSBC\, Goldman Sachs\, Societe Generale\, and Citigroup. His extensive background in the finance industry makes him a valuable resource for anyone looking to understand the intricacies of trading and investment.Join Michael as he shares his personal and professional journey\, offering insights and advice to help you navigate your own path in the finance world.&nbsp\;Event Details:Date and Time: February 18&nbsp\;at 4:00 p.m. to 5:00 p.m. ET\,Session Format: Virtual via TeamsWho Can Attend:&nbsp\;Freshmen\, sophomores and juniors who are pursuing an undergraduate degree. Candidates from all backgrounds and majors are welcome!Additional Information:&nbsp\;&nbsp\;You are welcome to attend as many sessions as you like. Find more details on our&nbsp\;events central page.Please Note – Campus recruiters focus on the recruitment and development of undergraduate talent for our summer internship programs. If you are a graduate student or young professional\, please check out our professional recruitment opportunities&nbsp\;here to learn more.
UID:129713-21864343@events.umich.edu
URL:https://events.umich.edu/event/129713
CLASS:PUBLIC
STATUS:CONFIRMED
CATEGORIES:
LOCATION:
CONTACT:
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BEGIN:VEVENT
DTSTAMP:20250303T063142
DTSTART;TZID=America/Detroit:20250218T160000
DTEND;TZID=America/Detroit:20250218T170000
SUMMARY:Careers / Jobs:USA - Campus - EY Next Steps: Winter Internship
DESCRIPTION:Are you interested in interning with EY’s Assurance or Tax practice\, but aren’t sure of your options? Join us for our upcoming information session where we’ll discuss our Winter Internship program. You’ll hear from Recruiters and EY Professionals to learn more about the logistics of the internship\, the many benefits it offers\, better understand how to make it work with your schedule and hear from previous Winter Interns. We hope to see you there!
UID:130639-21866470@events.umich.edu
URL:https://events.umich.edu/event/130639
CLASS:PUBLIC
STATUS:CONFIRMED
CATEGORIES:
LOCATION:
CONTACT:
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BEGIN:VEVENT
DTSTAMP:20250120T101346
DTSTART;TZID=America/Detroit:20250218T170000
DTEND;TZID=America/Detroit:20250218T193000
SUMMARY:Workshop / Seminar:February WISE Nights In
DESCRIPTION:Join WISE mentors and ambassadors for dinner! WISE Nights in are specifically designed to allow STEM students to meet other students in STEM\, foster connections\, and build their support network.
UID:130743-21866617@events.umich.edu
URL:https://events.umich.edu/event/130743
CLASS:PUBLIC
STATUS:CONFIRMED
CATEGORIES:Sessions
LOCATION:WISE Office
CONTACT:
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BEGIN:VEVENT
DTSTAMP:20250214T163808
DTSTART;TZID=America/Detroit:20250218T170000
DTEND;TZID=America/Detroit:20250218T180000
SUMMARY:Workshop / Seminar:Student Analysis Seminar: Introduction to Geophysical Fluid Dynamics
DESCRIPTION:Geophysical fluid dynamics refers to fluid dynamics on a rotating sphere\, and the mathematics behind GFD underlies our modern understanding of atmospheric and oceanic dynamics. In this talk\, I introduce some of the basic concepts and equation sets of geophysical fluid dynamics through the lens of the hierarchy of atmospheric motions.
UID:132793-21871840@events.umich.edu
URL:https://events.umich.edu/event/132793
CLASS:PUBLIC
STATUS:CONFIRMED
CATEGORIES:Mathematics
LOCATION:East Hall - 4096
CONTACT:
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