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We identified selective generation of such species as a key hurdle stymying development of these systems. To address this problem, we have leveraged electrochemistry to develop new synthetic transformations driven by organic radical ions. Electrochemistry offers not only an environmentally benign approach to promote redox events but also substantially simplifies the study of these unusual systems by enabling the exclusion of byproducts from oxidation or reductive generation of the key radical ion promoters. This seminar will describe multiple new platforms for synthetic reaction development based on electrochemically and photochemically generated organic radical ions.", "occurrence_notes":null, "guid":"149536-21906582@events.umich.edu", "permalink":"http:\/\/events.umich.edu\/event\/149536", "building_id":"1000158", "building_name":"Chemistry Dow Lab", "campus_maps_id":"34", "room":"CHEM 1400", "location_name":"Chemistry Dow Lab", "has_livestream":0, "cost":"", "tags":["Chemistry","Merck","Organic Chemistry","Science"], "website":"", "sponsors":[ { "group_name":"Department of Chemistry", "group_id":"3761", "website":"https:\/\/lsa.umich.edu\/chem" }, { "group_name":"Organic Chemistry", "group_id":"4389", "website":"" } ], "image_url":"", "styled_images":{ "event_thumb":"", "event_large":"", "event_large_2x":"", "event_large_lightbox":"", "group_thumb":"", "group_thumb_square":"", "group_large":"", "group_large_lightbox":"", "event_large_crop":"", "event_list":"", "event_list_2x":"", "event_grid":"", "event_grid_2x":"", "event_feature_large":"", "event_feature_thumb":"" }, "occurrence_count":1, "first_occurrence":21906582 } }