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Presented By: Department of Chemistry

Quantum Dynamics of Light and Matter

Arkajit Mandal

Placing molecules and materials between mirrors (or inside optical cavities) can enable the generation of exciting new chemical and physical phenomena in a highly controllable manner. In this talk, I will share a few of our theoretical works that demonstrate how photons can play the roles of a catalyst, a solvent, and a quantum degree of freedom beyond their usual role as a source of energy, to modify the chemical and physical properties of molecules and materials that are coupled to quantized radiation. First, I will discuss how quantum light-matter interactions can be utilized to modify the photochemistry of molecules and how a single photon can act as a catalyst to initiate multiple chemical reactions, leading to a quantum yield of more than one. Second, I will share our theoretical work that investigates how coupling molecular vibrations to vacuum radiation inside optical cavities can suppress or enhance the cleavage of specific chemical bonds, as seen in several recent experiments. I will share our theories that reveal that photons can act like solvents to enhance or suppress ground-state chemical kinetics. Next, I will show that quantum light-matter interactions can modify exciton-phonon interactions and can lead to the suppression of phonon-mediated decoherence. This enables fast ballistic transport in materials that are coupled to cavity radiation. I will share experimental results from our collaborators that confirm our theoretical predictions. Finally, I will share our theoretical framework, the quasi-diabatic propagation scheme, that allows for performing on-the-fly ab-initio quantum dynamics simulations, enabling us to investigate a wide range of problems, from photochemistry to polariton chemistry and beyond.

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