Presented By: Department of Chemistry
Reaction Development in the Amide Playground
Naoya Kumagai (Institute of Microbial Chemistry, Tokyo)
I will deliver 4 topics on the amide functionality;
1. Direct enolization chemistry of amide via designed asymmetric cooperative catalytic system. [JACS 2015, 137, 15929, etc.]
2. Utility of asymmetric amide-based ligand for asymmetric flow catalysis.
[ACIE 2013, 52, 6196, etc.]
3. Catalytic direct dehydrative amidation by a novel B3NO2 heterocyclic catalyst. [Nature Chem. doi:10.1038/nchem2708, etc.]
4. Twisting amide planarity: structural study and reactivity. [Chem. Sci. 2017, 8, 85, etc.]
These issues will be discussed with emphasis on synthetic utility and reaction mechanisms.
Naoya Kumagai (Institute of Microbial Chemistry, Tokyo)
1. Direct enolization chemistry of amide via designed asymmetric cooperative catalytic system. [JACS 2015, 137, 15929, etc.]
2. Utility of asymmetric amide-based ligand for asymmetric flow catalysis.
[ACIE 2013, 52, 6196, etc.]
3. Catalytic direct dehydrative amidation by a novel B3NO2 heterocyclic catalyst. [Nature Chem. doi:10.1038/nchem2708, etc.]
4. Twisting amide planarity: structural study and reactivity. [Chem. Sci. 2017, 8, 85, etc.]
These issues will be discussed with emphasis on synthetic utility and reaction mechanisms.
Naoya Kumagai (Institute of Microbial Chemistry, Tokyo)
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